Plausible Justification Trees: A Framework for Deep and Dynamic Integration of Learning Strategies

This article describes a framework for the deep and dynamic integration of learning strategies. The framework is based on the idea that each single-strategy learning method is ultimately the result of certain elementary inferences (like deduction, analogy, abduction, generalization, specialization, abstraction, concretion, etc.). Consequently, instead of integrating learning strategies at a macro level, we propose to integrate the different inference types that generate individual learning strategies. The article presents a concept-learning and theory-revision method that was developed in this framework. It allows the system to learn from one or from several (positive and/or negative) examples, and to both generalize and specialize its knowledge base. The method integrates deeply and dynamically different learning strategies, depending on the relationship between the input information and the knowledge base. It also behaves as a single-strategy learning method whenever the applicability conditions of such a method are satisfied.     

The linear landscape of external contextual languages

The class of external contextual languages isstrictly included in the class of linear languages. A reason for the strict inclusion in linear languages is that external contextual grammars generate languages in the exhaustive way: each sentential form belongs to the language of a grammar. In this paper we study the effect of adding various squeezing mechanisms to the basic classes of exhaustive contextual grammars. We obtain in this way a characterization of linear languages and a whole landscape of sublinear families. By restricting the contexts to be one-sided (only left-sided or only right-sided) we obtain a characterization of regular languages — here the subregular landscape reduces to two families.     

X-ray absorption fine structure investigations on heat-treated Cr-doped titania thin films

Chromium-doped titanium oxide thin films were investigated in the as-deposited state and after thermal treatment (723 K for 3 h in air). X-ray diffraction data revealed an improvement in film crystallinity induced by the thermal treatment. Extended X-ray absorption fine structure data revealed similar atomic neighboring around Cr atoms in both as-deposited and annealed samples. A lattice contraction of ~ 2% is observed in the annealed samples. The 67% enhancement of the amplitude of the Cr 1 s X-ray absorption fine structure pre-edge peak after thermal treatment, which is a sign of “dipole-forbidden” 1 s → 3 d transitions, suggests strong alteration in the number of Cr 3 d vacancies, in spite of similar Cr local environment in the two kinds of investigated samples. We discuss here the Cr⁺ → Cr⁴⁺ and Cr²⁺ → Cr⁶⁺ changes induced by thermal treatment, and/or the evolution in local structures without inversion center.Refractive index dispersion spectra in the visible wavelength domain allowed us to compute the values of the dispersion energy, the single-oscillator energy and the coordination number of Ti atoms in both as-deposited and annealed samples.     

Efficient photochromic transformation of a new fluorenyl diarylethene: one- and two-photon absorption spectroscopy

Efficient reversible phototransformation of a new diarylethene-fluorene derivative, 1,2-bis(5-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)-2-methylthiophen-3-yl)cyclopent-1-ene (1), was demonstrated in organic media under low-intensity laser excitation. Linear photophysical characterization of 1 was performed at room temperature in solvents of different polarity and viscosity. Significantly, close to unity quantum yield for the cyclization reaction of 1 was shown in nonpolar solutions. The lifetimes of the excited states of the open (OF) and closed (CF) forms of 1 were measured by a femtosecond transient absorption technique, and corresponding values of ～0.7 and ～0.9 ps were shown in dichloromethane (DCM), respectively. Degenerate two-photon absorption (2PA) spectra of the OF and CF of 1 were obtained over a broad spectral range by the open aperture Z-scan method under 1 kHz femtosecond excitation. The values of 2PA cross sections of the OF in DCM (～50-70 GM) were found to increase up to 1 order of magnitude (～600 GM) after cyclization to the CF. The nature of cyclization and cylcoreversion processes were investigated by quantum chemistry with employment of DFT-based methods implemented in the Gaussian'09 program. The potential of 1 for application in optical data storage was shown using poly(methyl methacrylate)-doped films and two-photon fluorescence microscopy readout.     

Rheological Aspects of Spanish Honeys

The purpose of this work was to investigate the rheological behavior of Spanish honeys under different conditions (at different temperatures and concentrations). All the samples were characterized to determine their physicochemical (moisture, ⁰Brix, pH, ash, conductivity, color, total acidity, diastase activity, 5-hydroxymethylfurfural content, sugar content) and thermal (glass transition temperature) profiles. The honeys samples (80.4–82 ⁰Brix) behaved as Newtonian fluid; as expected, their viscosity increased with the solid content and decreased with the temperature. Two experimental viscosity models (Arrhenius and Vogel–Taumman–Fulcher) were checked using the experimental data to correlate the influence of temperature on honey viscosity. A simplified model was proposed to describe the combined effect of the temperatures and concentrations (⁰Brix) on the viscosity of Spanish honeys. The dynamic viscosity and complex viscosity had the same magnitude at 40 °C, 45 °C, and 50 °C for of all the samples and the Cox Merz rule could be applied at these temperatures.     

Remembrance of Petre T. Frangopol (1933–2020) the promoter of scientometrics in Romania

Scientometrics - The article is an obituary aimed to pay tribute to Petre T. Frangopol, a brilliant Romanian scientist (chemist and biophysicist). He had many fields of interest: Chemistry,...     

Investigation of metallic nanoparticles adsorbed on the QCM sensor by SEM and AFM techniques

Quartz crystal microbalance (QCM) is known as a very sensitive device used for determination of mass quantity adsorbed on sensor surface. Its detection limits are in the range of ng cm\(^{-2}\). The adsorption mechanism of metallic nanoparticles on QCM sensor was investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). This study aims to highlight the importance of QCM applications in nanoparticles deposition field. The layers formed through adsorption process, induced by the oscillations of the QCM sensor, were investigated by AFM for surface topography and for particle mean size values. The morphology of layers and nanoparticles dimensions were determined by SEM. For a more complex investigation of the nanoparticles adsorption mechanism, the chemical composition of layers was achieved using SEM coupled with energy dispersive X-ray spectrometer (SEM-EDS). This preliminary research involved a new approach in characterization of metallic nanoparticles layers to achieve functional assembled monolayers.     

Studies on the electronic transport properties of some organic semiconductors in thin films

The investigated compounds are some derivatives of orthotolidin-N,N-bis (4-aminobenzene-2-sulphonic) acid. The temperature dependences of the electrical conductivity and Seebeck coefficient are studied on the thin films deposited from dimethylformamide solution onto glass substrates. It is known that the investigated compounds have typical semiconducting properties. The values of some important parameters of the films (thermal activation energy of electrical conduction, concentrations and mobilities of charge carriers) have been determined. The correlations between some of these parameters and molecular structure of the respective compounds are discussed.     

Languages generated by P systems with active membranes

We propose an alternative approach to generate languages by means of P systems: building up an appropriate representation for a string by means of a corresponding membrane structure and then generating the string by visiting the membrane structure according to a well-specified strategy. To this aim, we consider P systems with active membranes, allowing membrane creation or division or duplication and dissolution, where the output of a computation may be obtained either by visiting the tree associated with the membrane structure, or by following the traces of a specific object, called traveller, or sending out the objects. For each of these approaches, we provide characterizations of recursively enumerable languages based on P systems that use different sets of operations for modifying the membrane structure. Francesco Bernardini: He started his Ph.D. at the University of Sheffield in December 2002 after having previously got a master degree in Computer Science from the University of Pisa in Italy. His research is dedicated to the study of theoretical aspects of membrane computing (P systems) and discrete models of biological systems based on P systems. Marian Gheorghe, Ph.D.: His main research interests are in computational models and their applications to software modelling and testing, formal specifications of agent based systems, software engineering. He was investigating computational power of various generative devices (regular, context-free, fully initial; grammar systems; L-systems and variants). He is currently interested in natural computing (membrane calculus) and biological modelling.     

The power of communication: P systems with symport/antiport

In the attempt to have a framework where the computation is done by communication only, we consider the biological phenomenon of trans-membrane transport of couples of chemicals (one say symport when two chemicals pass together through a membrane, in the same direction, and antiport when two chemicals pass simultaneously through a membrane, in opposite directions). Surprisingly enough, membrane systems without changing (evolving) the used objects and with the communication based on rules of this type are computationally complete, and this result is achieved even for pairs of communicated objects (as encountered in biology). Five membranes are used; the number of membranes is reduced to two if more than two chemicals may collaborate when passing through membranes. Andrei Paun: He graduated the Faculty of Mathematics of Bucharest University in 1998, received his M.Sc. degree from The University of Western Ontario in 1999, and since then he is a PhD student in the Computer Science Department of University of Western Ontario, London, Canada (under the guidance of prof. Sheng Yu). The topic of his thesis is Molecular Computing (especially, DNA and Membrane Computing), but his research interests also include neural networks, implementing automata, combinatorics on words. Gheorghe Paun: (the proud father of two sons, including the first author of this paper) He is a member of the Romanian Academy, working as a senior researcher in the Institute of Mathematics of the Romanian Academy, Bucharest, and as a Ramon y Cajal researcher in Rovira i Virgili University of Tarragona, Spain. He is one of the most active authors in (the theory of) DNA Computing, (co)author of many papers in this area, (co)author and (co)editor of several books. In 1998 he has initiated the area of Membrane Computing. Other research interests: regulated rewriting, grammar systems, contextual grammars, combinatorics on words, computational linguistics.